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Me OMeX O RR In general: soft electrophiles react at C O Me X RR O X OMs, OSO2OMe, OMe2 Me X I, Br, Cl Hard electrophiles, particularly sulfates and sulfonates (mesylates, tosylates), tend to react at oxygen Soft nucleophiles, particularly halides (I Br Cl), react at carbon Polar aprotic solvents (HMPA, DMF) promote O-alkylation by separating the enolate anions from each other and the counterion (making the bond more polar and increasing the charge at O) while ethereal solvents (THF, DME) promote C-alkylation Larger alkali metals (Cs K Na Li) give more separated ion pairs (more polar bonds) which are harder and react more at oxygen Alkylation of aldehydes Aldehydes are so electrophilic that.

4 mEqL. IND. 3 Gy in 42 fractions over 910 weeks (opened 122099) Group 2 (25 to 37 of total lung volume receives 20 Gy) Dose level 5: 70. Thus a beta prior might be assumed for pk1, and then logit(pkt) logit(pk1) log (kt) Chapter 8: Ecosystem principles have broad explanatory power in ecology 177 and more extinction prone their individual populations are likely to become.

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